| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sibusiso Raymond Nkosi | - | Member | — | People's Assembly |
| Sifiso Brilliance Ngomane | - | Member | — | People's Assembly |
| Sinah Lewis | - | Member | — | People's Assembly |
| Siphephelo Bright Khumalo | - | Member | — | People's Assembly |
| Solly Malatsi | - | - | — | |
| Solly Tshepiso Msimanga | - | Member | — | People's Assembly |
| Stevens Mokgalapa | - | Member | — | People's Assembly |
| Suzette Fourie | - | Member | — | People's Assembly |
| Sydney Peter Smith | - | Member | Mar 2014 | People's Assembly |
| Sizwe Wiseman Mchunu | - | Member | — | People's Assembly |
| Solly Nkhi | - | Member | — | People's Assembly |
| Sophia Mamy Mogola | - | Member | — | People's Assembly |
| Stephanus Johannes Roos | - | Member | — | People's Assembly |
| Stephen Rudolf Schormann | - | Member | — | People's Assembly |
| Stuart Bruce Pringle | - | Member | — | People's Assembly |
| Stuart Brian Farrow | - | Member | — | People's Assembly |
| Sybrandt Rynardt De Beer | - | Member | — | People's Assembly |
| Sithembiso Ngema | - | Member | — | People's Assembly |
| S J Masango | - | Member | — | People's Assembly |
| Sello Petrus Motswenyane | - | Member | — | People's Assembly |
| Stephen James Moore | - | Member | — | People's Assembly |
| Tandeka Gqada | - | Member | — | People's Assembly |
| Tania Lynette Campbell | - | Member | — | People's Assembly |
| Tarryn Ann Wantenaar | - | Member | — | People's Assembly |
| Tandi Gloria Mpambo-Sibhukwana | - | Member | — | People's Assembly |