| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Safiyia Hajeera Stanfley | - | Member | — | People's Assembly |
| Salomon Maritz Van Dyk | - | Member | — | People's Assembly |
| Samantha Nair | - | Member | — | People's Assembly |
| Sandra Ethel Van Den Berg | - | Member | — | People's Assembly |
| Sandra Fillis | - | Member | — | People's Assembly |
| Sanelisiwe Pretty Ncama | - | Member | — | People's Assembly |
| Santosh Vinita Kalyan | - | Member | — | People's Assembly |
| Selebatso Rebecca Mogorosi | - | Member | — | People's Assembly |
| Semakaleng Patricia Kopane | - | Member | — | People's Assembly |
| Shane Maas | - | Member | — | People's Assembly |
| Sarel Jacobus Francois Marais | - | Member | — | People's Assembly |
| Sepuki Johannes Monyetshwale | - | Member | — | People's Assembly |
| Sephalane David Sebelebele | - | Member | — | People's Assembly |
| Shahid Esau | - | Member | — | People's Assembly |
| Sharne Muriel Jacobs | - | Member | — | People's Assembly |
| Sharon Lynn Van Niekerk | - | Member | — | People's Assembly |
| Shonisani Sellinah Mulaudzi | - | Member | — | People's Assembly |
| Shontel Veronica Asbury | - | Member | — | People's Assembly |
| Sejamotopo Charles Motau | - | Member | — | People's Assembly |
| Selamuel Reuben Pitseng | - | Member | — | People's Assembly |
| Serena Jacob | - | Member | — | People's Assembly |
| Shamaladevi Ramdhunee | - | Member | — | People's Assembly |
| Sharna Gail Fernandez | - | Member | — | People's Assembly |
| Shaun Shaw Moffitt | - | Member | — | People's Assembly |
| Sheery Su-Huei Cheng | - | Member | — | People's Assembly |