| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Samuel Msimango | - | Member | — | People's Assembly |
| Sandi Simon Cenenda | - | Member | — | People's Assembly |
| Sandla Goqwana | - | Member | — | People's Assembly |
| Saraphinah Phuti Setati | - | Member | — | People's Assembly |
| Seipati Florence Ndlovu | - | Member | — | People's Assembly |
| Selikane Aaron Seobi | - | Member | — | People's Assembly |
| Sello Jerry Mokgoko | - | Member | — | People's Assembly |
| Sello Silvester Seiphetlho | - | Member | — | People's Assembly |
| Setshabe Kate Serage | - | Member | — | People's Assembly |
| Shadrack Lerato Mogalaka | - | Member | — | People's Assembly |
| Sello Paul Phulo | - | Member | — | People's Assembly |
| Sikhumbuzo Welcome Mtatambi | - | Member | — | People's Assembly |
| Sbusiso Fransisco Xaba | - | Member | — | People's Assembly |
| Seropane Senyane Alton Mphethi | - | Member | — | People's Assembly |
| Sewela Francinah Mabena | - | Member | — | People's Assembly |
| Sibongile Vidah Ragimana | - | Member | — | People's Assembly |
| Sikhumbuzo Jubase | - | Member | — | People's Assembly |
| Simon Malathi Mdluli | - | Member | — | People's Assembly |
| Simon Tshabalala | - | Member | — | People's Assembly |
| Sindile Portia Matlala | - | Member | — | People's Assembly |
| Sindisiwe Nkosi | - | Member | — | People's Assembly |
| Siphelo Somdaka | - | Member | — | People's Assembly |
| Siphosenkosi Genius Tshabangu | - | Member | — | People's Assembly |
| Sithembele Melvin Mtshamba | - | Member | — | People's Assembly |
| Siphiwe Sikhakhane | - | Member | — | People's Assembly |