| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Shipokasa Paulus Mashatile | - | Member | — | People's Assembly |
| Siboniso Armstrong Duma | - | Member | — | People's Assembly |
| Sibusiso Innocent Malaza | - | Member | — | People's Assembly |
| Sikhakhane Nokuthula | - | Member | — | People's Assembly |
| Sikhumbuzo Eric Kholwane | - | Member | — | People's Assembly |
| Simanga Happy Mbuyane | - | Member | — | People's Assembly |
| Simphiwe Donatus Bekwa | - | Member | — | People's Assembly |
| Sindiswa Thelmonia Magwandana | - | Member | — | People's Assembly |
| Sizani Mtshotane | - | Member | — | People's Assembly |
| Sizwe Isaak Mbalo | - | Member | — | People's Assembly |
| Sipho Joseph Gcabashe | - | Member | — | People's Assembly |
| Sobhuza Ernest Dlamini | - | Member | — | People's Assembly |
| Solani Patrick Baloyi | - | Member | — | People's Assembly |
| Susan Comber Van der Merwe | - | Member | until Oct 2013 | People's Assembly |
| Sussana Rebecca Tsebe | - | Member | — | People's Assembly |
| Siphiwo Sam Mazosiwe | - | Member | — | People's Assembly |
| Sipho Kroma | - | Member | — | People's Assembly |
| Siyabonga Cyprian Cwele | - | Member | — | People's Assembly |
| Siyazi Gratefull Tyatyam | - | Member | — | People's Assembly |
| Sizeni Grace Bothman | - | Member | — | People's Assembly |
| Sibongiseni Maxwell Dhlomo | - | Member | — | People's Assembly |
| Sochayile Khanyile | - | Member | — | People's Assembly |
| Solomon Patrick Mabilo | - | Member | — | People's Assembly |
| Sophia Theresa Williams-De Bruyn | - | Member | — | People's Assembly |
| S Shiceka | - | Member | — | People's Assembly |