| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sentle Lavius Emmanuel Fenyane | - | Member | — | People's Assembly |
| Senzeni Zokwana | - | Member | — | People's Assembly |
| Setlamorago Godfrey Thobejane | - | Member | — | People's Assembly |
| Sheila Coleen Nkhensani Shope-Sithole | - | Member | — | People's Assembly |
| Sheila Coleen Nkhensani Sithole | - | Member | — | People's Assembly |
| Shepherd Malusi Mayatula | - | Member | — | People's Assembly |
| Sheshile Virginia Nkwanyana | - | Member | — | People's Assembly |
| Sibongile Pearm Tsoleli | - | Member | — | People's Assembly |
| Sipho Caiphas Nkosi | - | Member | — | People's Assembly |
| Sediane Danny Montsitsi | - | Member | — | People's Assembly |
| Shadrack Lapologang Tlhaole | - | Member | — | People's Assembly |
| Sharome Renay Van Schalkwyk | - | Member | — | People's Assembly |
| Sharon Winona Davids | - | Member | — | People's Assembly |
| Shela Paulina Boshielo | - | Member | — | People's Assembly |
| Shiaan-Bin Huang | - | Member | — | People's Assembly |
| Sibongile Mchunu | - | Member | — | People's Assembly |
| Sicelo Hamilton Gqobana | - | Member | — | People's Assembly |
| Sifiso Musawenkosi Sonjica | - | Member | — | People's Assembly |
| Sarah Matawana Mlamleli | - | Member | — | People's Assembly |
| Sello Albert Tleane | - | Member | — | People's Assembly |
| Sello Meshack Maetso | - | Member | — | People's Assembly |
| Doreen Zamantungwa Sbusisiwe Senokoanyane | - | Member | — | People's Assembly |
| Sepeke Davis Matji | - | Member | — | People's Assembly |
| Shahidabibi Shaikh | - | Member | — | People's Assembly |
| Sheilla Tembalam Xego-Sovita | - | Member | — | People's Assembly |